2017 - Seminars
Department of Chemistry and Biochemistry-Summer and Fall 2017Unless noted otherwise, All Friday Seminars will begin at 3:10 pm and take place in the Byker Auditorium-Chemistry Biochemistry Building.
Monday, May 8th
Ms. Ashley Beckstead will defend her Ph.D in Chemistry beginning with a seminar titled "Excited-State Dynamics of Biological Molecules in Solution: Photoinduced Charge Transfer in Oxidatively Damaged DNA and Deactivation of Violacein in Viscous Solvents." 9 am Byker Auditorium. Ms. Beckstead is co-advised by Professors Rob Walker and Bern Kohler.
Wednesday, May 10thMr. David Skowron will defend his Ph.D in Chemistry beginning with a seminar titled "Subnanosecond Emission from Model DNA Oligomers Characterized though Time-Correlated Single Photon Counting Spectroscopy." Byker Auditorium at 1 pm. David is co-advised by Professors Rob Walker and Bern Kohler.
Wednesday, May 17th 1 pm
John Sauson, head of Sales for Agilent Mass Spectrometry will give a presentation: New Developments in Biological Mass Spectrometry. Professor Brian Bothner to host.
Wednesday, May 17th 3 pm
Ms. Amanda Fuchs will present her research in a 4th graduate student seminar. Byker Auditorium at 3 pm. Amanda works in the lab of Professor Valérie Copié.
Thursday, June 1st
Ms. Jessica Ennist will defend her Ph.D in Chemistry beginning with a seminar (title to follow). Byker Auditorium at 9 am. Jessica is completing her Ph.D in the laboratory of Professor Mary Cloninger.
Wednesday, July 12th
Mr. Eric Massaro will present a 3rd year graduate student seminar (title TBD). 1 pm in the Byker Auditorium. Eric works in the laboratory of Professor Erik Grumstrup.
Department of Chemistry and Biochemistry-Fall 2017
Friday September 1
Dr. Leslie Murray - Professor Jen DuBois host
Friday September 8
Brian Hoffman - Professor Joan Broderick host
Friday September 15
Dr. Ron Shen - Graduate Student Association host
Friday September 22
Dr. Gerrick Lindberg - Professor Sharon Neufeldt host
Friday September 29
Catherine Murphy - Professor Tim Minton host
Friday, October 6
John Kozarich of ActivX Biosciences, Joan Broderick host
Friday, October, 13
Ed Rosenburg (UM) Robert Szilagyi host
Friday, October 20
Dr. George Stanley from Louisiana State University will present "Bimetallic Cooperativity in Catalysis: Twice the Fun!" 3:10 pm in the Byler. Professor Sharon Neufeldt is the host.
Abstract: Homobimetallic rhodium complexes using the binucleating tetraphosphine ligand racemic-(Et2PCH2CH2)(Ph)PCH2P(Ph)(CH2CH2PEt2), et,ph-P4, are highly active and selective hydroformylation catalysts for a variety of 1-alkenes. We have investigated the nature of the bimetallic cooperativity in this novel catalyst via extensive in situ FT-IR, NMR, kinetic, isotopic labeling experiments, and DFT computational studies, all of which indicate that the key bimetallic catalyst in acetone is a unique dicationic Rh(+2) oxidation state complex, [rac-Rh2(m-H)2(CO)2(et,ph-P4)]2+. Unfortunately, the NMR studies clearly indicate that this catalyst system is very susceptible to deactivating fragmentation reactions.
When a 30% water/acetone solvent system is used for hydroformylation deprotonation of the dicationic dihydride species occurs generating a less active, but far more fragmentation resistant bimetallic catalyst proposed to be [Rh2(m-H)(CO)2(et,ph-P4)]+, which out-preforms the dicationic catalyst. Based on the fragmentation problem a new, far more strongly coordinating P4 ligand that uses 1,2-phenylene based chelating groups has been designed, synthesized, and characterized. Studies on bimetallic complexes based on this new P4 ligand will be discussed.
Friday, October 27
Regan Thompson (Northwestern) Matt Cook host
Friday, November 3
Dr. Steve Patterson (University of Minnesota), Garrett Moraski host
Friday November 10 -Holiday
Friday November 17 open
Friday, Dec 1
Scott Shaw (Iowa State) Rob Walker host
Friday, January 12 -open
Friday January 19 -open
Friday January 26-
Levi Stanley (Matt Cook)
Friday February 3 -open
Friday, February 16
Dr. Melanie Sanford (Michigan) . Sharon Neufeldt host.
Friday February 23
Graduate Recruiting Speaker, Dr. Sunshine Silver, Assistant Professor, North Park University, Chicago.