Announcements

  The CHMY 361 Website is now at D2L:    https://ecat1.montana.edu/

Handouts 2018

  • Handout #1 Syllabus 2018
  • Handout#1a Homework#1
  • Handout#2 Objectives for Exam 1
  • Handout#3 Homework#2-updated 10:50 am 24sep18
  • Handout#4 Homework#3
  • Handout#5 Objectives for Exam 2
  • Handout 6: Homework #4 updated 1:05 pm 23oct18
  • Handout#7 Homework#5 updated Tue 10:45 am; due Mon. Nov. 5
  • Handout#8 Objectives for Exam 3
  • Handout#9: Homework #6 (Updated 10:35 am, Mon. Nov. 19)
  • Handout#10: Roadmap for Last 4 Weeks
  • Handout#11: Homework # 7 (updated Thur. Nov 22)
  • Handout#12: Objectives for Exam 4
  • Handout#13: How to Estimate Your Final Grade
  • Handout#14: Objectives and Advice for Final Exam

Lectures 2018

Lec 1 Mon 26aug19 Course Introduction
Lec 2 Tue  28aug18 System, Surroundings, Universe, Heat vs. Work
Lec 3 Thur 30aug18 Bio-work; Calculating work and pressure.
Lec 4  Fri   31aug18 Heat Capacity; Ideal gas Kinetic Energy vs. Temperature
Lec 5 Tue  4sep18 State, State functions, reversible vs. irreversible paths 
Lec 6 Thur  6sep18  Reversible Isothermal expansion; Work from KE of molecules; Enthalpy;Cp
Lec 7 Fri     7sep18  Cp;  Chemical Reactions; Heats of formation; Standard States; Hesses Law; Bond Enthalpies
Lec 8 Mon 10sep18  Homework help; Partial Pressure; Vapor Pressure
Lec 9 Tue 11sep18  Boiling in detail; more Vapor Pressure; Intro 2nd Law and Carnot Cycle
Lec 10 Thur 13sep18  Heat Pump vs. Heat Engine; calculating entropy: dS = dqrev/T
Lec 11 Fri  14sep18  Using 2nd Law; 3rd Law&Molecular Interpretation
Lec 12 Thur 21sep17  "Free" Energy Functions; The Fundamental Equation
Lec 13 Fri 22sep17 Partial Derivatives I: G vs T and P
Lec 14 Mon 24sep18 Partial Derivatives II
Lec 15 Tue 26sep17 Non-covalent "reactions", proteins
Lec 16 Thur 27sep18 More proteins; DNA;chemical potential; Gibbs energy of reactions and equilibr
 Lec 17 Fri  28sep18 Qualitative and Quantitative LeChatelier; Units of Q; Finding Keq
Lec 18 Mon  1oct18 The Real Q; Activity; activity coef; Biol. Standard state; Temperature Dependence of Keq:Van't Hoff 
Lec 19 Tue  2oct18  More Activity,Van't Hoff; duplex DNA association/dissociation; Buffers
Lec 20 Thur 4oct18 Boltzmann Distribution=Gibbs Keq; Equipartition Principle; Heat Capacity and Quantum Mech.
Lec 21 Fri 5oct18 Hesses Law for Table 4.3; Overview of energy in biology; Electrochem. I
Lec 22 Mon 8oct18 Electrochem II:Finding E0 and delta G0 for a reaction;Nernst Eq.
Lec 23 Tue 9oct18 Intro to Phase Equilibria; Solvent transfers
Lec 24 Mon 15oct18 Vapor Pressure vs T; Solute Transfers:Henry's Law
Lec 25 Tue 16Oct 18: Phase Rule;Partition coefficients;
Lec 26 Thur 18Oct18 Surface Tension, Hydrophobic Effect;Membranes; Transmembrane equilibria; Na+,K+ pumping
Lec 27 Fri 19Oct18 Colligative Properties
Lec 28 Mon 22Oct18: Colligative II:Osmotic Press; Molecular Speeds:Magnitude and Distribution
Lec 29 Tue  23Oct18: Collision rates;Mean free path; Diffusion and Frictional Coef.
Lec 30 Thur 25Oct18 Sedimentation; Viscosity;
Lec 31 Fri 26Oct18 Protein Electrophoresis
Lec 32 Mon 29Oct18 DNA Electrophoresis; Kinetics I
Lec 33 Tue 30Oct18 More First Order; Mechanisms;TemperatureDependence;Diffusion Controlled
Lec 34 Thur 1Nov18 Photochemistry; Enzymes I
Lec 35 Fri 2Nov18 Enzyme kinetics II; Electrostatics
Lec 36 Mon 5Nov18 Light; Beers Law; Protein UV
Lec 37 Tue 13nov18 Beer's Law; Fluorescence I;Jablonski, Kasha'sRule; Lifetime; Quenching; Phosphorescence;FRET I
Lec 38 Thur 15nov18 Resonance;FRET; DNA Hypochromism; single molecule fluorescence; vision;CD;
Lec 39 Fri 16nov18 Vibrational spectroscopy; NMR I
Lec 40 Mon 19nov18 NMR II; MRI I
Lec 41 Tue 20nov18 Understanding NMR with Boltzmann and Quantum mechanics
Lec 42 Mon 26nov18 More pulsed NMR; Intro to Quantum Mechanics; Quantum Concepts
Lec 43 Tue 27nov18 Quantum Concepts, wave nature of particles;BlueSkies-RedSunsets
Lec 44 Mon 3dec18 Climate Science
Lec 45 Thur 6dec18 Review 1
Lec 46 Thur 7dec18 Review 2

Reading Assignments 2018

Chapter 2. See Handout #1 (Syllabus)

Chapter 3.
Lectures 9-10 Tues.,Thurs   Sept. 12 and 14:  pp 55-61
Lecture 11  Fri 15sep17  pp 62-71
Lecture 12   Thur.  21sep17: pp72-75
Lecture 13   Fri.  22sep17: pp 75-80(top half)
Lecture 14   Mon. 25sep17 pp 87-90(Partial Derivatives)
Lecture 15   Tue. 26sep17 pp 80-87(Non-Covalent “Reactions”)

 Chapter 4.
Lecture 16   Thur: 27sep18 pp 101-104 Gibbs Energy
Lecture 17    Fri.   28sep18  pp 104(bottom)-107 Gibbs Energy and Kequil
Lecture 18    Mon.  1oct18     pp 108(bottom)-119 (Non-ideal gases, activity, standard states, biochemical standard state)
Lecture 19    Tue.   2oct18     pp 126(bottom)-129 (Kequil vs. T;; 140(bottom)-142 (DNA melting T); 133-134 ( buffer

Chapter 5.
Lecture 20    Thur.  4oct18     pp 162,191 Boltzmann distribution; p 24 equipartition, quantum effects on heat capacity
Lecture 21    Fri.     5oct18 pp 135-138 Thermo. of metabolism;Chapter 7241-242 Electrochem. cells and work

Chapter 7

Lecture 22   Mon.  8oct18 pp 243-247 Standard reduction potentials, free energies, and Nernst equation.

Reading Assignments 2017

Chapter 3.
Lectures 9-10 Tues.,Thurs   Sept. 12 and 14:  pp 55-61
Lecture 11  Fri 15sep17  pp 62-71
Lecture 12   Thur.  21sep17: pp72-75
Lecture 13   Fri.  22sep17: pp 75-80(top half)
Lecture 14   Mon. 25sep17 pp 87-90(Partial Derivatives)
Lecture 15   Tue. 26sep17 pp 80-87(Non-Covalent “Reactions”)

Chapter 4.
Lecture 16   Thur: 28sep17 pp 101-104 Gibbs Energy
Lecture 17    Fri.   29sep17  pp 104(bottom)-107 Gibbs Energy and Kequil
Lecture 18    Mon.  2oct17     pp 108(bottom)-119 (Non-ideal gases, activity, standard states, biochemical standard state)
Lecture 19    Tue.   3oct17     pp 126(bottom)-129 (Kequil vs. T;; 140(bottom)-142 (DNA melting T); 133-134 ( buffers)

Chapter 5.
Lecture 20    Thur.  5oct17     pp 162,191 Boltzmann distribution; p 24 equipartition, quantum effects on heat capacity
Lecture 21    Fri.     6oct17 pp 135-138 Thermo. of metabolism;Chapter 7241-242 Electrochem. cells and work

Chapter 7

Lecture 22   Mon.  9oct17 pp 243-247 Standard reduction potentials, free energies, and Nernst equation.

Chapter 6
Lecture 23   Tue.  10oct17 196-204 Phase equilibria I
Lecture 24   Mon Oct 16: pp 200(bottom)-207 Vapor Pressure vs T; Solute Transfers:Henry's Law
Lecture 25  Tue    Oct 17: p200 Phase Rule;pp207-213 Partition coefficients; Scatchard Plots;Hill coef.
Lecture 26  Thur  Oct 19: pp214-224; Surface Tension, Hydrophobic Effect;Membranes;
Oct 19: Ch. 7pp247-252 Transmembrane equilibria; Na+,K+ pumping
Lecture 27  Fri      Oct 20: pp248-252 Colligative properties

Chapter 8

Lecture 28  Mon  Oct 23: Ch 8: pp 252-156 Maxwell Boltzmann (optional); pp264-268:Ave speed;collisions per second;mean free path.
Lecture 29 Tue   Oct 24:   pp 269-76 Diffusion and Frictional Coef.:
Lecture 30 Thur Oct 26:  pp 285-287, 292-294: Viscosity, pp278-281, 283:Sedimentation 
Lecture 31 Fri    Oct 27:   pp 292-294: Protein Electrophoresis
Lecture 32 Mon Oct 30:  pp 288-291: DNA Electrophoresis and sequencing
Chapter 9Lecture 33 Tue Oct 31:  pp 305-316 First order kinetics; 327-329;337-338: Mechanisms; 333bottom-335:Microscopic reversibility;
pp 338-340:Temperature Dependence
Lecture 34  Thur Nov 2 pp354-355: Diffusion controlled reactions; pp 358-363: Photochemistry;
Chapter 10 pp 378-381: Enzymes I
Lecture 35  Fri  Nov 3 pp 382-385: Enzymes II; Chapter 12  466-469: Electrostatics; Chapter 13 pp 489-493:Light I
Lecture 36  Mon  Nov 6 pp 382-385: Enzymes III; Chapter 13 pp 489-502:Light-molecule interactions and Beer-Lambert Law
Tue Nov.6 Review for Exam 3 (which is on THURSDAY, NOV 9)
Thur Nov. 9 EXAM 3
Friday Nov. 10 Veterans Day Holiday (classes don't meet)
Lecture 37  Mon  Nov 13 pp 502-519 Protein & DNA UV spectra; DNA Hypochromism; Fluorescence; Lifetime; Quenching; FRET;  Single-molecule fluorescence
Lecture 38  Tue  Nov  14 pp 520-525: CD;
Lecture 39  Thur Nov 16  pp 526-530  Vibrational spectroscopy; Chapter 14 pp 539-543: NMR
Lecture 40  Fri     Nov 17  pp 544-548: NMR spectrum and Chemical shifts; pp 562(bottom)-566 MRI

Lecture 41  Mon Nov 20 Review MRI for HW problem; then back to pp 542, 544-546 with Boltzmann and quantum ideas

Lecture 42 Tue   Nov 21

Exam  Solutions 2017
Exam#1 Solutions
Exam#2 Solutions
Exam #3 Solutions

Exam #4 Solutions

Final Exam

Old Exam Keys

Exam Keys 2018

Exam 1

 

Links


Direct questions to pcallis@montana.edu

Room 55 CBB
Phone 994-5414

 

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